Fingerprint detection and using intercalated CdSe nanoparticles on non-porous surfaces

Anal Chim Acta. 2014 Feb 17:812:228-35. doi: 10.1016/j.aca.2014.01.015. Epub 2014 Jan 15.

Abstract

A fluorescent nanocomposite based on the inclusion of CdSe quantum dots in porous phosphate heterostructures, functionalized with amino groups (PPH-NH2@CdSe), was synthesized, characterized and used for fingerprint detection. The main scopes of this work were first to develop a friendly chemical powder for detecting latent fingerprints, especially in non-porous surfaces; their further intercalation in PPH structure enables not to spread the fluorescent nanoparticles, for that reason very good fluorescent images can be obtained. The fingerprints, obtained on different non-porous surfaces such as iron tweezers, mobile telephone screen and magnetic band of a credit card, treated with this powder emit a pale orange luminescence under ultraviolet excitation. A further image processing consists of contrast enhancement that allows obtaining positive matches according to the information supplied from a police database, and showed to be more effective than that obtained with the non-processed images. Experimental results illustrate the effectiveness of proposed methods.

Keywords: Fingerprints; Fluorescent nanoparticles; Log-normal model; Nonlinear fitting; Quantum dots.