Copper-catalyzed coupling reaction of arylhydrazines and trialkylphosphites

Sheng-Yan Chen; Run-Sheng Zeng; Jian-Ping Zou; Olayinka Taiwo Asekun

doi:10.1021/jo4022474

Copper-catalyzed coupling reaction of arylhydrazines and trialkylphosphites

J Org Chem. 2014 Feb 7;79(3):1449-53. doi: 10.1021/jo4022474. Epub 2014 Jan 27.

Authors

Sheng-Yan Chen¹, Run-Sheng Zeng, Jian-Ping Zou, Olayinka Taiwo Asekun

Affiliation

¹ Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Material Science, Soochow University , Suzhou 215123, People's Republic of China.

PMID: 24467414
DOI: 10.1021/jo4022474

Abstract

A novel CuO-catalyzed coupling reaction of arylhydrazines with trialkyl phosphites to afford arylphosphonates is described. The reaction proceeded at 80 °C in air without external reductants, oxidants, and ligands.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Catalysis
Copper / chemistry*
Hydrazines / chemistry*
Ligands
Organophosphorus Compounds / chemical synthesis*
Organophosphorus Compounds / chemistry*
Oxidants / chemistry*
Phosphites / chemistry*

Substances

Hydrazines
Ligands
Organophosphorus Compounds
Oxidants
Phosphites
Copper