Double layer effects at nanosized electrodes

Faraday Discuss. 2013:164:339-48. doi: 10.1039/c3fd00050h.

Abstract

This paper discusses numerical simulations of double layer effects at shrouded electrodes with dimensions below 100 nm. Special focus is given to the surface charge on the shrouding material. The Poisson-Nernst-Planck equations are solved to study the effects on the limiting current arising from the electrical double layer of the shrouding.