2,2'-[(1,3,4-Thia-diazole-2,5-di-yl)bis-(sulfanedi-yl)]diaceto-nitrile

Joel T Mague; Mehmet Akkurt; Shaaban K Mohamed; Ahmed M M El-Saghier; Mustafa R Albayati

doi:10.1107/S1600536813032194

2,2'-[(1,3,4-Thia-diazole-2,5-di-yl)bis-(sulfanedi-yl)]diaceto-nitrile

Acta Crystallogr Sect E Struct Rep Online. 2013 Nov 30;69(Pt 12):o1855. doi: 10.1107/S1600536813032194.

Authors

Joel T Mague¹, Mehmet Akkurt², Shaaban K Mohamed³, Ahmed M M El-Saghier⁴, Mustafa R Albayati⁵

Affiliations

¹ Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.
² Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey.
³ Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England ; Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
⁴ Department of Chemistry, Faculty of Science, Sohag University, 82524 Sohag, Egypt.
⁵ Kirkuk University, College of Science, Department of Chemistry, Kirkuk, Iraq.

Abstract

In the title compound, C6H4N4S3, the 1,3,4-thia-diazole ring is essentially planar, with an r.m.s. deviation of 0.001 Å. The two N-C-S-C torsion angles in the mol-ecule are -23.41 (15) and 0.62 (14)°. One aceto-nitrile group is above the plane of the 1,3,4-thia-diazole ring and the other is below it, indicating syn and anti orientations. In the crystal, C-H⋯N hydrogen bonds link the molecules into ribbons along [010].