2-N-Benzyl-2,6-dide-oxy-2,6-imino-3,4-O-iso-propyl-idene-d-allono-nitrile

Acta Crystallogr Sect E Struct Rep Online. 2013 Nov 13;69(Pt 12):o1772. doi: 10.1107/S1600536813030584.

Abstract

X-ray crystallography firmly established the relative stereochemistry of the title compound, C16H20N2O3. The acetonide ring adopts an envelope conformation with one of the O atoms as the flap and the piperidine ring adopts a slightly twisted boat conformation. The absolute configuration was determined by use of d-ribose as the starting material. The compound exists as O-H⋯O hydrogen-bonded chains of mol-ecules running parallel to the b axis.