Rubidium penta-aqua-(l-serine)cobalt(II) hexa-hydrogenhexa-molybdocobaltate(III) l-serine monosolvate deca-hydrate

Jun Iijima; Haruo Naruke; Hiroshi Takiyama

doi:10.1107/S1600536813028304

Rubidium penta-aqua-(l-serine)cobalt(II) hexa-hydrogenhexa-molybdocobaltate(III) l-serine monosolvate deca-hydrate

Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 19;69(Pt 11):m612-3. doi: 10.1107/S1600536813028304.

Authors

Jun Iijima¹, Haruo Naruke², Hiroshi Takiyama³

Affiliations

¹ Department of Chemical Engineering, School of Engineering, Tokyo University of Agriculture and Technology, 2-24-16, Naka-cho, Koganei-city, Tokyo, Japan.
² Chemical Resouces Laboratory, Tokyo Institute of Technology, 4259, Nagatsuta, Midori-ku, Yokohama-city, Kanagawa, Japan.
³ Division of Applied Chemistry, Institute of Engineering, Tokyo University of Agriculture and Technology, 2-24-16, Naka-cho, Koganei-city, Tokyo, Japan.

Abstract

The Co(2+) ion in the title compound, Rb[Co(C3H7NO3)(H2O)5][H6CoMo6O24]·C3H7NO3·10H2O, is coordinated by five water mol-ecules and one O-monodentate l-serine ligand in a slightly distorted octahedral geometry. The Rb(+) ion is irregularly coordinated by nine O atoms. In the crystal, the [H6Co(III)Mo6O24](3-) polyanions are stacked along the b-axis direction, mediated by bridging Rb-O bonds. N-H⋯O and O-H⋯O hydrogen bonds are observed involving the l-serine mol-ecules.