Tris[4-bromo-2-(methyl-imino-meth-yl)phenolato-κ(2) N,O]cobalt(III)

Qiu-Ping Huang; Chun-Lian Zhang; Ru-Xia Zhao; Li Yang; Xi-Fu Jiang

doi:10.1107/S1600536813027591

Tris[4-bromo-2-(methyl-imino-meth-yl)phenolato-κ(2) N,O]cobalt(III)

Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 16;69(Pt 11):m601. doi: 10.1107/S1600536813027591.

Authors

Qiu-Ping Huang¹, Chun-Lian Zhang¹, Ru-Xia Zhao¹, Li Yang¹, Xi-Fu Jiang¹

Affiliation

¹ College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, People's Republic of China.

Abstract

In the title compound, [Co(C8H7BrNO)3], the Co(III) ion is coordinated in a slightly distorted octa-hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl-imino-meth-yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2) and 62.9 (2)°. In the crystal, mol-ecules are linked by pairs of weak C-H⋯Br hydrogen bonds, forming inversion dimers.