Colourimetric and fluorescent detection of oxalate in water by a new macrocycle-based dinuclear nickel complex: a remarkable red shift of the fluorescence band

Md Mhahabubur Rhaman; Frank R Fronczek; Douglas R Powell; Md Alamgir Hossain

doi:10.1039/c3dt53467g

Colourimetric and fluorescent detection of oxalate in water by a new macrocycle-based dinuclear nickel complex: a remarkable red shift of the fluorescence band

Dalton Trans. 2014 Mar 28;43(12):4618-21. doi: 10.1039/c3dt53467g.

Authors

Md Mhahabubur Rhaman¹, Frank R Fronczek, Douglas R Powell, Md Alamgir Hossain

Affiliation

¹ Department of Chemistry and Biochemistry, Jackson State University, Jackson, MS 39212, USA. alamgir.hossain@jsums.edu.

Abstract

A new macrocycle-based dinuclear nickel chemosensor selectively binds oxalate anions both in solution and the solid state, displaying a remarkable red shift of the fluorescence band with a visible colour change in water at physiological pH in the presence of an external dye.

Publication types

Research Support, N.I.H., Extramural
Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

Colorimetry
Coordination Complexes / chemistry*
Eosine Yellowish-(YS) / chemistry
Fluorescence
Fluorescent Dyes / chemistry
Hydrogen-Ion Concentration
Light
Nickel / chemistry*
Oxalates / analysis*
Oxalates / chemistry
Water / analysis*

Substances

Coordination Complexes
Fluorescent Dyes
Oxalates
Water
Nickel
Eosine Yellowish-(YS)

Abstract

Publication types

MeSH terms

Substances

Grants and funding