Multichromophoric dye-sensitized solar cells (DSSCs) comprised of a supramolecular zinc-phthalocyanineperyleneimide (ZnPc···PMI) dyad convert light to electrical energy with much higher power conversion efficiency (PCE = 2.3%) and incident-photon-to-current-efficiency (IPCE = ca. 40%) than the devices made of individual dyes.