A new type of double-chain based 3D lanthanide(III) metal-organic framework demonstrating proton conduction and tunable emission

Min Zhu; Zhao-Min Hao; Xue-Zhi Song; Xing Meng; Shu-Na Zhao; Shu-Yan Song; Hong-Jie Zhang

doi:10.1039/c3cc48764d

A new type of double-chain based 3D lanthanide(III) metal-organic framework demonstrating proton conduction and tunable emission

Chem Commun (Camb). 2014 Feb 21;50(15):1912-4. doi: 10.1039/c3cc48764d. Epub 2014 Jan 9.

Authors

Min Zhu¹, Zhao-Min Hao, Xue-Zhi Song, Xing Meng, Shu-Na Zhao, Shu-Yan Song, Hong-Jie Zhang

Affiliation

¹ State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, China. hongjie@ciac.ac.cn.

PMID: 24407038
DOI: 10.1039/c3cc48764d

Abstract

A new type of 3D lanthanide(III) metal-organic framework directly constructed by double-chain motifs was synthesized. It shows a proton conductivity of 1.6 × 10(-5) S cm(-1) at 75 °C at 97% RH, and tunable emission including white light.