Two- and one-step cooperative spin transitions in Hofmann-like clathrates with enhanced loading capacity

Lucía Piñeiro-López; Maksym Seredyuk; M Carmen Muñoz; José A Real

doi:10.1039/c3cc48595a

Two- and one-step cooperative spin transitions in Hofmann-like clathrates with enhanced loading capacity

Chem Commun (Camb). 2014 Feb 21;50(15):1833-5. doi: 10.1039/c3cc48595a. Epub 2014 Jan 8.

Authors

Lucía Piñeiro-López¹, Maksym Seredyuk, M Carmen Muñoz, José A Real

Affiliation

¹ Institut de Ciència Molecular (ICMol), Departament de Química Inorgànica, Universitat de València, C/Catedrático José Beltrán Martínez, 2, 46980 Paterna, Valencia, Spain. jose.a.real@uv.es.

PMID: 24402508
DOI: 10.1039/c3cc48595a

Abstract

Structural, magnetic, calorimetric and Mössbauer studies of the cooperative spin crossover naphthalene and nitrobenzene clathrates of the novel Fe(II) Hofmann-like porous metal-organic framework {Fe(bpb)[Pt(CN)4]}·2Guest are described (bpb = bis(4-pyridyl)butadiyne).