Skeletal recombination reaction of N-fused pentaphyrin(1.1.1.1.1) via bromination

Org Lett. 2014 Jan 17;16(2):327-9. doi: 10.1021/ol403242z. Epub 2013 Dec 17.

Abstract

N-Fused [22]pentaphyrin(1.1.1.1.1) transformed into recombined N-fused pentaphyrin bromide after treatment with N-bromosuccinimide. This bromide was highly reactive to nucleophiles to give the corresponding substituted products including aminated, oxidized, and unsubstituted derivatives.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Bromosuccinimide / chemistry*
  • Catalysis
  • Crystallography, X-Ray
  • Electron Spin Resonance Spectroscopy
  • Hydrocarbons, Brominated / chemistry*
  • Molecular Conformation
  • Molecular Structure
  • Oxidation-Reduction
  • Porphyrins / chemistry*

Substances

  • Hydrocarbons, Brominated
  • Porphyrins
  • Bromosuccinimide