Three-dimensional electrodes offer great advantages, such as enhanced ion and electron transport, increased material loading per unit substrate area, and improved mechanical stability upon repeated charge-discharge. The origin of these advantages is discussed and the criteria for ideal 3D electrode structure are outlined. One of the common features of ideal 3D electrodes is the use of a 3D carbon- or metal-based porous framework as the structural backbone and current collector. The synthesis methods of these 3D frameworks and their composites with redox-active materials are summarized, including transition metal oxides and conducting polymers. The structural characteristics and electrochemical performances are also reviewed. Synthesis of composite 3D electrodes is divided into two types - template-assisted and template-free methods - depending on whether a pre-made template is required. The advantages and drawbacks of both strategies are discussed.
Keywords: 3D electrodes; energy storage; ion diffusion and electron transport length; template-assisted synthesis; template-free synthesis.
© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.