A yellow-emitting Na2CaP2O7:Mn(2+)phosphors have been synthesized by solid state reaction. The crystal structure, photoluminescence properties as well as concentration quenching mechanism have been investigated. The (4)T1-(6)A1 emission of Mn(2+)in Na2CaP2O7 phosphor ranges from 500 to 650 nm and exhibits a red shift while increasing the Mn(2+)concentration. The crystal field strength is calculated based on the combination of excitation spectrum and Tanabe-Sugano diagram. The chromaticity coordinates of Na2CaP2O7:Eu(2+), Mn(2+)phosphors were discussed in order to develop the potential application in white light-emitting diodes (LEDs).
Keywords: Concentration quenching; Critical distance; Phosphor; Tanabe–Sugano diagram.
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