Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

Chem Commun (Camb). 2014 Jan 21;50(6):728-30. doi: 10.1039/c3cc47699e. Epub 2013 Nov 29.

Abstract

The reactivity of a rhenium complex containing an NAD(+) model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph3C(+).

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Carbon Dioxide / chemistry*
  • Coordination Complexes / chemistry*
  • Ligands
  • Models, Biological
  • Models, Molecular
  • NAD / chemistry*
  • Oxidation-Reduction
  • Rhenium / chemistry*

Substances

  • Coordination Complexes
  • Ligands
  • NAD
  • Carbon Dioxide
  • Rhenium