Abstract
The reactivity of a rhenium complex containing an NAD(+) model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph3C(+).
Publication types
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Carbon Dioxide / chemistry*
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Coordination Complexes / chemistry*
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Ligands
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Models, Biological
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Models, Molecular
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NAD / chemistry*
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Oxidation-Reduction
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Rhenium / chemistry*
Substances
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Coordination Complexes
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Ligands
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NAD
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Carbon Dioxide
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Rhenium