Filtration-wet transferred transparent conducting films of mm long carbon nanotubes grown using water-assisted chemical vapor deposition

J Nanosci Nanotechnol. 2013 Nov;13(11):7413-7. doi: 10.1166/jnn.2013.7875.

Abstract

Transparent conducting films (TCF) made up from carbon nanotubes (CNTs) have a tremendous potential in replacing the indium tin oxide films. Compare to single wall CNTs multiwall CNTs are more metallic and are more suitable candidate for the TCF. In this letter we report the use of selectively grown mm-scale, few-wall, vertically aligned CNTs for the fabrication of TCF. Water-assisted chemical vapor deposition was used to grow the mm-scale CNTs within short growth time. A special post-growth water-vapor treatment allowed us to remove the catalyst-free CNT forest very easily from the substrate and use it for the further process. A filtration-wet transfer process was used to form the TCF. The TCF shows sheet resistance of 228 omega/sq. at 72% transparency (at 550 nm). The ratio of optical conductivity to dc conductivity was observed in between 0.21 to 0.25 for below 80% transmission.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallization / methods*
  • Electric Conductivity
  • Gases / chemistry
  • Macromolecular Substances / chemistry
  • Materials Testing
  • Membranes, Artificial*
  • Molecular Conformation
  • Nanotubes, Carbon / chemistry*
  • Nanotubes, Carbon / ultrastructure*
  • Particle Size
  • Surface Properties
  • Titanium / chemistry*
  • Ultrafiltration / methods*
  • Water / chemistry*
  • Wettability

Substances

  • Gases
  • Macromolecular Substances
  • Membranes, Artificial
  • Nanotubes, Carbon
  • Water
  • titanium dioxide
  • Titanium