Abstract
Metal-organic supercontainers (MOSCs) represent a new family of synthetic receptors derived from container precursors and featuring both endo and exo cavities. A neutral MOSC has been functionalized into an anionic container by incorporating sulfo groups. The anionic MOSC exhibits cavity-specific binding properties in both solid state and solution.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Calixarenes / chemistry*
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Crystallography, X-Ray
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Metals / chemistry*
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemistry*
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Phenols / chemistry*
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Stereoisomerism
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Sulfinic Acids / chemistry*
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Surface Properties
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Thermodynamics
Substances
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Metals
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Organometallic Compounds
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Phenols
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Sulfinic Acids
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Calixarenes
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sulfonyl chloride