Isomorphs, hidden scale invariance, and quasiuniversality

Phys Rev E Stat Nonlin Soft Matter Phys. 2013 Oct;88(4):042139. doi: 10.1103/PhysRevE.88.042139. Epub 2013 Oct 24.

Abstract

This paper first establishes an approximate scaling property of the potential-energy function of a classical liquid with good isomorphs (a Roskilde-simple liquid). This "pseudohomogeneous" property makes explicit that-and in which sense-such a system has a hidden scale invariance. The second part of the paper gives a potential-energy formulation of the quasiuniversality of monatomic Roskilde-simple liquids, which was recently rationalized in terms of the existence of a quasiuniversal single-parameter family of reduced-coordinate constant-potential-energy hypersurfaces [J. C. Dyre, Phys. Rev. E 87, 022106 (2013)]. The new formulation involves a quasiuniversal reduced-coordinate potential-energy function. A few consequences of this are discussed.

Publication types

  • Research Support, Non-U.S. Gov't