Third-generation breathing metal-organic framework with selective, stepwise, reversible, and hysteretic adsorption properties

Suresh Sanda; Srinivasulu Parshamoni; Sanjit Konar

doi:10.1021/ic402095u

Third-generation breathing metal-organic framework with selective, stepwise, reversible, and hysteretic adsorption properties

Inorg Chem. 2013 Nov 18;52(22):12866-8. doi: 10.1021/ic402095u. Epub 2013 Oct 30.

Authors

Suresh Sanda¹, Srinivasulu Parshamoni, Sanjit Konar

Affiliation

¹ Department of Chemistry, IISER Bhopal, Bhopal 462023, India.

PMID: 24171473
DOI: 10.1021/ic402095u

Abstract

A new 2D interdigitated and highly flexible, breathing metal-organic framework has been synthesized through a diffusion technique by using the aldrithiol linker and pyromellitate ligand. The compound shows selective, stepwise, reversible, and hysteretic adsorption properties for CO2 gas and H2O, MeOH, and CH3CN vapors.