Abstract
A series of end-to-end azido-bridged perovskite-type compounds [(CH3)nNH4-n][Mn(N3)3] (n = 1-4) were synthesized and characterized. Structural phase transitions indicating the general lattice flexibility were observed and confirmed by the crystal structures of different phases. These materials show cation-dependent magnetic ordering at up to 92 K and magnetic bistability near room temperature.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Azides / chemical synthesis
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Azides / chemistry*
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Bridged-Ring Compounds
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Calcium Compounds / chemical synthesis
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Calcium Compounds / chemistry*
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Calorimetry, Differential Scanning
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Cations / chemistry*
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Crystallography, X-Ray
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Drug Stability
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Magnetic Fields
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Magnetic Resonance Spectroscopy
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Models, Molecular
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Molecular Conformation
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Oxides / chemical synthesis
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Oxides / chemistry*
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Temperature
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Titanium / chemistry*
Substances
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Azides
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Bridged-Ring Compounds
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Calcium Compounds
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Cations
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Oxides
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perovskite
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Titanium