Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells

Nanoscale. 2013 Dec 7;5(23):11686-91. doi: 10.1039/c3nr01542d.

Abstract

We report for the first time the use of a perovskite (CH3NH3PbI3) absorber in combination with ZnO nanorod arrays (NRAs) for solar cell applications. The perovskite material has a higher absorption coefficient than molecular dye sensitizers, gives better solar cell stability, and is therefore more suited as a sensitizer for ZnO NRAs. A solar cell efficiency of 5.0% was achieved under 1000 W m(-2) AM 1.5 G illumination for a solar cell with the structure: ZnO NRA/CH3NH3PbI3/spiro-MeOTAD/Ag. Moreover, the solar cell shows a good long-term stability. Using transient photocurrent and photovoltage measurements it was found that the electron transport time and lifetime vary with the ZnO nanorod length, a trend which is similar to that in dye-sensitized solar cells, DSCs, suggesting a similar charge transfer process in ZnO NRA/CH3NH3PbI3 solar cells as in conventional DSCs. Compared to CH3NH3PbI3/TiO2 solar cells, ZnO shows a lower performance due to more recombination losses.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Coloring Agents / chemistry
  • Electron Transport
  • Iodides / chemistry*
  • Lead / chemistry*
  • Light
  • Methylamines / chemistry*
  • Nanotubes / chemistry*
  • Solar Energy*
  • Zinc Oxide / chemistry*

Substances

  • Coloring Agents
  • Iodides
  • Methylamines
  • Lead
  • methylamine
  • Zinc Oxide