Copper-catalyzed direct oxysulfonylation of alkenes with dioxygen and sulfonylhydrazides leading to β-ketosulfones

Chem Commun (Camb). 2013 Nov 11;49(87):10239-41. doi: 10.1039/c3cc45803b.

Abstract

The first copper-catalyzed oxysulfonylation reaction of alkenes with dioxygen and sulfonylhydrazides for the construction of β-ketosulfones has been developed under mild conditions without any ligand or additive.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkenes / chemistry*
  • Catalysis
  • Copper / chemistry*
  • Hydrazines / chemistry*
  • Ketones / chemical synthesis*
  • Ketones / chemistry
  • Molecular Structure
  • Organometallic Compounds / chemistry*
  • Oxygen / chemistry*
  • Sulfones / chemical synthesis*
  • Sulfones / chemistry*

Substances

  • Alkenes
  • Hydrazines
  • Ketones
  • Organometallic Compounds
  • Sulfones
  • Copper
  • Oxygen