A 3d-4f heterometallic 3D POMOF based on lacunary Dawson polyoxometalates

Dalton Trans. 2013 Dec 14;42(46):16328-33. doi: 10.1039/c3dt51983j.

Abstract

A novel compound, Na2[Ce4(H2O)22(dpdo)5](Mn2HP2W15O56)2·8H2O (1) (dpdo = 4,4'-bipyridine-N,N'-dioxide) with 3d-4f heterometallic 3D POMOF that can be described as a self-penetrating (4,4,6)-connected net topology, has been isolated via a stepwise method, and its magnetic and electrocatalytic properties have been investigated.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Catalysis
  • Crystallography, X-Ray
  • Magnetics
  • Molecular Conformation
  • Organometallic Compounds / chemical synthesis
  • Organometallic Compounds / chemistry*
  • Tungsten Compounds / chemistry*

Substances

  • Organometallic Compounds
  • Tungsten Compounds
  • polyoxometalate I