Bottom-up assembly of ultrathin sub-micron size metal-organic framework sheets

Rie Makiura; Oleg Konovalov

doi:10.1039/c3dt51703a

Bottom-up assembly of ultrathin sub-micron size metal-organic framework sheets

Dalton Trans. 2013 Dec 7;42(45):15931-6. doi: 10.1039/c3dt51703a. Epub 2013 Sep 24.

Authors

Rie Makiura¹, Oleg Konovalov

Affiliation

¹ Nanoscience and Nanotechnology Research Center, Research Organization for the 21st Century, Osaka Prefecture University, Sakai, Osaka 599-8570, Japan. r-makiura@21c.osakafu-u.ac.jp.

PMID: 24061409
DOI: 10.1039/c3dt51703a

Abstract

A solution-based two-dimensional interfacial reaction between 5,10,15,20-tetra(4-pyridyl)-porphinato zinc(II) (ZnTPyP, 1) and Cu(NO3)2·3H2O, 2, results in the assembly of uniform preferentially oriented highly crystalline metal-organic framework nanosheets, NAFS-21 that have sub-micron planar size and mono-molecular thickness.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Copper / chemistry*
Metalloporphyrins / chemistry*
Models, Molecular
Nanostructures / chemistry*
Nitrates / chemistry*
Organometallic Compounds / chemistry*

Substances

Metalloporphyrins
Nitrates
Organometallic Compounds
tris(porphinato)zinc(II)
Copper
copper(II) nitrate