A robust amino-functionalized titanium(iv) based MOF for improved separation of acid gases

Sébastien Vaesen; Vincent Guillerm; Qingyuan Yang; Andrew D Wiersum; Bartosz Marszalek; Barbara Gil; Alexandre Vimont; Marco Daturi; Thomas Devic; Philip L Llewellyn; Christian Serre; Guillaume Maurin; Guy De Weireld

doi:10.1039/c3cc45828h

A robust amino-functionalized titanium(iv) based MOF for improved separation of acid gases

Chem Commun (Camb). 2013 Oct 3;49(86):10082-4. doi: 10.1039/c3cc45828h.

Authors

Sébastien Vaesen¹, Vincent Guillerm, Qingyuan Yang, Andrew D Wiersum, Bartosz Marszalek, Barbara Gil, Alexandre Vimont, Marco Daturi, Thomas Devic, Philip L Llewellyn, Christian Serre, Guillaume Maurin, Guy De Weireld

Affiliation

¹ Service de Thermodynamique, Faculté Polytechnique, Université de Mons, 20 Place du Parc, Mons, 7000, Belgium. guy.deweireld@umons.ac.be.

PMID: 24045671
DOI: 10.1039/c3cc45828h

Abstract

A combination of adsorption, microcalorimetry, infra-red spectroscopy and modeling has been implemented to reveal the potential of the H2S resistant amino-functionalized Ti MOF MIL-125 porous solid for the concomitant elimination of CO2 and H2S from biogas and natural gas.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Adsorption
Amines / chemistry*
Calorimetry
Carbon Dioxide / chemistry
Chemistry Techniques, Analytical / methods*
Gases / chemistry*
Hydrogen Sulfide / chemistry
Infrared Rays
Organic Chemistry Phenomena
Porosity
Titanium / chemistry*

Substances

Amines
Gases
Carbon Dioxide
Titanium
Hydrogen Sulfide