Effect of incorporating BisGMA resin on the bonding properties of silane and zirconia primers

J Prosthet Dent. 2013 Nov;110(5):402-7. doi: 10.1016/j.prosdent.2013.04.005. Epub 2013 Sep 3.

Abstract

Statement of problem: Some silane primers and some zirconia primers contain extra resins such as bisphenol A glycol dimethacrylate (BisGMA) in their formulations for better wetting. No studies exist on the bonding properties of zirconia and silane primers, which contain extra resins.

Purpose: The purpose of this study was to investigate the effect of incorporating BisGMA resin on the bonding properties of silane and zirconia primers.

Material and methods: Silica-base lithium disilicate was etched and treated with BisGMA-incorporated Porcelain Primer, unmodified Porcelain Primer, or resin-containing Kerr Silane. Zirconia ceramic was airborne-particle abraded and treated with BisGMA-incorporated Monobond Plus, unmodified Monobond Plus, or BisGMA-containing ZPrime Plus. After primer treatment and cleaning with ethanol, the contact angles were measured to determine surface change (n=10). Shear bond strength tests were also performed to measure the adhesion strength between resin cements and ceramic surfaces (n=10). Data were statistically analyzed by 1-way ANOVA followed by the Tukey multiple comparison as a post hoc test (significance level .05).

Results: The incorporation of BisGMA resin did not significantly influence the bond strength or contact angle of the zirconia primer (P>.05), but it did significantly reduce those of the silane primer (P<.05). Resin-containing Kerr Silane (22 degrees, 23 MPa) had a similar contact angle and higher bond strength than the control (21 degrees, 18 MPa), but lower than Porcelain Primer (88 degrees, 34 MPa). Resin-containing ZPrime Plus (75 degrees, 29 MPa) had a similar contact angle and higher bond strength than both Monobond Plus (74 degrees, 18 MPa) and the control (15 degrees, 4 MPa).

Conclusions: The addition of BisGMA resin significantly inhibited the efficacy of silane-containing porcelain primers but did not affect that of phosphate-containing zirconia primers.

MeSH terms

  • Acid Etching, Dental / methods
  • Adhesiveness
  • Aluminum Oxide / chemistry
  • Bisphenol A-Glycidyl Methacrylate / chemistry*
  • Dental Bonding*
  • Dental Etching / methods
  • Dental Porcelain / chemistry
  • Dental Stress Analysis / instrumentation
  • Humans
  • Hydrofluoric Acid / chemistry
  • Materials Testing
  • Methacrylates / chemistry
  • Resin Cements / chemistry*
  • Shear Strength
  • Silanes / chemistry*
  • Stress, Mechanical
  • Surface Properties
  • Temperature
  • Time Factors
  • Water / chemistry
  • Wettability
  • Zirconium / chemistry*

Substances

  • Duo-Link
  • Methacrylates
  • Resin Cements
  • Silanes
  • lithia disilicate
  • Water
  • Dental Porcelain
  • methacryloxypropyltrimethoxysilane
  • Bisphenol A-Glycidyl Methacrylate
  • methacryloyloxydecyl dihydrogen phosphate
  • Zirconium
  • Aluminum Oxide
  • Hydrofluoric Acid
  • zirconium oxide