Nanocrystalline starch grafted palladium(II) complex for the Mizoroki-Heck reaction

Dalton Trans. 2013 Oct 28;42(40):14454-9. doi: 10.1039/c3dt51685g.

Abstract

Nanocrystalline starch produced from the acid hydrolysis of gelatinized starch has been used for the first time to support palladium(II) ethylenediamine complex. The nanocrystalline starch supported Pd(II) complex was found to be an efficient and efficiently recycled catalyst for the Mizoroki-Heck reaction of furans and thiophenes with styrenes under mild reaction conditions.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Catalysis
  • Ethylenediamines / chemistry
  • Furans / chemistry*
  • Molecular Structure
  • Nanoparticles / chemistry*
  • Organometallic Compounds / chemical synthesis
  • Organometallic Compounds / chemistry*
  • Palladium / chemistry*
  • Starch / chemistry*
  • Styrenes / chemistry
  • Thiophenes / chemistry*

Substances

  • Ethylenediamines
  • Furans
  • Organometallic Compounds
  • Styrenes
  • Thiophenes
  • Palladium
  • ethylenediamine
  • Starch