Ultrathin nanosheets of vanadium diselenide: a metallic two-dimensional material with ferromagnetic charge-density-wave behavior

Angew Chem Int Ed Engl. 2013 Sep 27;52(40):10477-81. doi: 10.1002/anie.201304337. Epub 2013 Aug 16.

Abstract

A new metallic 2D material with high electrical conductivity (1×10(3) S m(-1)) consists of VSe2 ultrathin nanosheets with 4-8 Se-V-Se atomic layers. This is the first 2D transition-metal dichalcogenide with intrinsic room-temperature ferromagnetism. The nanosheets increase the charge-density-wave transition temperature to 135 K by dimensional reduction.

Keywords: charge density waves; metallic behavior; room temperature ferromagnetism; ultrathin nanosheets; vanadium selenide.