In this paper, temperature variations are detected thanks to an enhanced nano-optical pyroelectric sensor. Sensing is obtained with the pyroelectric effect of lithium niobate (LN) in which, a suitable air-membrane photonic crystal cavity has been fabricated. The wavelength position of the cavity mode is tuned 11.5 nm for a temperature variation of only 32 °C. These results agree quite well with 3D-FDTD simulations that predict tunability of 12.5 nm for 32 °C. This photonic crystal temperature sensor shows a sensitivity of 0.359 nm/°C for an active length of only ~5.2 μm.