ortho-Acetoxylation of phosphonic and phosphoric monoacids via Pd(II) catalysis

J Org Chem. 2013 Sep 6;78(17):8826-32. doi: 10.1021/jo4011188. Epub 2013 Aug 16.

Abstract

A simple and efficient method is developed for Pd-catalyzed ortho-acetoxylation using organophosphates, namely, benzylic phosphonic and aryl phosphoric monoacids, as the directing group.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetates / chemical synthesis*
  • Acetates / chemistry
  • Catalysis
  • Molecular Structure
  • Organometallic Compounds / chemistry*
  • Palladium / chemistry*
  • Phosphoric Acids / chemistry*
  • Phosphorous Acids / chemistry*

Substances

  • Acetates
  • Organometallic Compounds
  • Phosphoric Acids
  • Phosphorous Acids
  • Palladium
  • phosphoric acid