Innovative/efficient finishing systems for imparting multi-functional properties to cotton/polyester and viscose/polyester blends were developed. Factors affecting the extent of functionalization including type and concentration of the nano-hybrid, i.e. silver nanoparticles/polyvinyl pyrolidone hybrid (Ag-NP's/PVP) or zinc oxide nanoparticles/hyperbranched polyamide-amine hybrid (ZnO-NP's/HBPAA), concentration of Basic Blue 9, or chitosan and sequence of treatment using citric acid as cross-linker were reported. Loading of β-CD, with its hydrophobic cavities, onto the cross-linked substrates and subsequent treatment with Neem-oil, Lavender-oil or 4-hydroxybenzophenone was also studied. The obtained products exhibit a remarkable easy care, antibacterial and/or UV-blocking functional properties. The improvement in the imparted properties and durability to wash is governed by type and amount of loaded active ingredients. Mode of interactions was suggested, and surface modifications together with composition of selected samples were also confirmed by SEM images and EDX spectra.
Keywords: Antibacterial; Cellulosic/polyester blends; Chitosan; Easy-care finishing; MCT-βCD Multi-functional finishes; Nano-hybrids; UV-protection; “Host–guest” inclusion complexes.
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