Gradual electroforming and memristive switching in Pt/CuO(x)/Si/Pt systems

Nanotechnology. 2013 Aug 16;24(32):325202. doi: 10.1088/0957-4484/24/32/325202. Epub 2013 Jul 18.

Abstract

We report a memristive switching effect in Pt/CuOx/Si/Pt devices prepared by the rf sputtering technique at room temperature. Differently from other Cu-based metal filament switching systems, a gradual electroforming process, marked by a gradual increase of the device resistance and a gradual decrease of the device capacitance, was observed in the current-voltage and capacitance characteristics. After the gradual electroforming, the devices show a uniform memristive switching behavior. By Auger electron spectroscopy analysis, a model based on the thickness change of the SiOx layer at the CuOx/Si interface and Cu ion migration is proposed for the gradual electroforming and uniform memristive switching, respectively. This work should be meaningful for the preparation of forming-free and homogeneous memristive devices.

Publication types

  • Research Support, Non-U.S. Gov't