Photodynamics of stress in clamped nematic elastomers

Phys Rev E Stat Nonlin Soft Matter Phys. 2013 Jun;87(6):062503. doi: 10.1103/PhysRevE.87.062503. Epub 2013 Jun 17.

Abstract

We describe the complex time dependence of the buildup of force exerted by a clamped photoelastomer under illumination. Nonlinear (non-Beer) absorption leads to a bleaching wave of a significant cis isomer dye concentration deeply penetrating the solid with a highly characteristic dynamics. We fit our experimental response at one temperature to obtain material parameters. Force-time data can be matched at all other temperatures with no fitting required; our model provides a universal description of this unusual dynamics. The description is unambiguous since these are clamped systems where gross polymer motion is suppressed as a possible source of anomalous dynamics. Future experiments are suggested.

Publication types

  • Research Support, Non-U.S. Gov't