Regiodivergent N-C and N-N aryl coupling reactions of indoloterpenes and cycloether formation mediated by a single bacterial flavoenzyme

Angew Chem Int Ed Engl. 2013 Aug 19;52(34):9040-3. doi: 10.1002/anie.201303733. Epub 2013 Jul 10.

Authors

Martin Baunach¹, Ling Ding, Torsten Bruhn, Gerhard Bringmann, Christian Hertweck

Affiliation

¹ Dept. of Biomolecular Chemistry, Leibniz Institute for Natural Product Research and Infection Biology, HKI, Beutenbergstr. 11a, 07745 Jena, Germany.

PMID: 23843280
DOI: 10.1002/anie.201303733

No abstract available

Keywords: alkaloids; aryl coupling; flavoproteins; indolosesquiterpenes; radicals.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Alkaloids
Amines
Catalysis
Ethers, Cyclic / chemistry*
Flavoproteins / chemistry*
Models, Molecular
Molecular Conformation
Molecular Structure
Terpenes / chemistry*

Substances

Alkaloids
Amines
Ethers, Cyclic
Flavoproteins
Terpenes