Abstract
The first total syntheses of spirobacillenes A and B were achieved concisely. The key transformation leading to spirobacillene A features a biomimetic intramolecular phenol-enol oxidative coupling reaction, and that leading to spirobacillene B highlights a bio-inspired intramolecular indole-ketone enolate oxidative coupling reaction.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Biomimetics
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Cyclopentanes / chemical synthesis*
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Indoles / chemistry
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Iodides / chemistry
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Ketones / chemistry
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Oxides / chemistry
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Phenols / chemistry
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Silver Compounds / chemistry
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Spiro Compounds / chemical synthesis*
Substances
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Cyclopentanes
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Indoles
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Iodides
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Ketones
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Oxides
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Phenols
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Silver Compounds
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Spiro Compounds
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spirobacillene A
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spirobacillene B
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disilver oxide