Abstract
We wish to report a novel preparation method for Gemsurf analogs as well as dicarboxylic acid-type Gemini surfactant from Diels-Alder adducts of 2-trimethylsilyloxy-1,3-butadiene, in which ozone oxidation is adopted to convert C=C double bond to dicarboxylic acid without any additional oxidant.
MeSH terms
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Butadienes / chemistry
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Chemistry Techniques, Synthetic / methods
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Cycloaddition Reaction*
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Dicarboxylic Acids / chemistry*
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Oxidation-Reduction
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Ozone / chemistry*
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Surface-Active Agents / chemical synthesis*
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Surface-Active Agents / chemistry*
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Trimethylsilyl Compounds / chemistry
Substances
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Butadienes
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Dicarboxylic Acids
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Surface-Active Agents
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Trimethylsilyl Compounds
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Ozone