3-[(1-Bromo-naphthalen-2-yl)meth-oxy]-5,5-di-methyl-cyclo-hex-2-enone

Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 20;69(Pt 5):o758. doi: 10.1107/S160053681301026X. Print 2013 May 1.

Abstract

In the title compound, C19H19BrO2, the cyclo-hexenone ring adopts an envelope conformation with the C atom bearing the methyl substituents as the flap. In the crystal, weak π-π stacking is observed between parallel aromatic rings of adjacent mol-ecules, the centroid-centroid distance being 3.694 (6) Å. The entire bromonaphthylmethyl unit is disordered over two orientations, with a site-occupancy ratio of 0.5214 (19):0.4786 (19).