2-[3-(4-Bromo-phenyl)-5-(4-fluoro-phenyl)-4,5-di-hydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia-zole

Bakr F Abdel-Wahab; Hanan A Mohamed; Seik Weng Ng; Edward R T Tiekink

doi:10.1107/S1600536813010039

2-[3-(4-Bromo-phenyl)-5-(4-fluoro-phenyl)-4,5-di-hydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia-zole

Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 17;69(Pt 5):o735. doi: 10.1107/S1600536813010039. Print 2013 May 1.

Authors

Bakr F Abdel-Wahab¹, Hanan A Mohamed, Seik Weng Ng, Edward R T Tiekink

Affiliation

¹ Applied Organic Chemistry Department, National Research Centre, Dokki, 12622 Giza, Egypt.

Abstract

In the title compound, C24H17BrFN3S, the pyrazole ring is almost planar (r.m.s. deviation = 0.043 Å), with all but the perpendicular fluoro-benzene ring substituents [dihedral angle = 77.9 (3)°] being very approximately coplanar [dihedral angle with the 2-thienyl ring = 19.4 (3)° and with the bromo-benzene ring = 20.3 (3)°; dihedral angle between the 2-thienyl and attached phenyl ring = 11.0 (4)°], so that the mol-ecule has a T-shape. In the crystal, supra-molecular chains along the b-axis direction are sustained by C-H⋯S and C-Br⋯π inter-actions.