3-Methyl-4-{(E)-[4-(methyl-sulfan-yl)benzyl-idene]amino}-1H-1,2,4-triazole-5(4H)-thione

B K Sarojini; P S Manjula; Gurumurthy Hegde; Dalbir Kour; Vivek K Gupta; Rajni Kant

doi:10.1107/S1600536813009690

3-Methyl-4-{(E)-[4-(methyl-sulfan-yl)benzyl-idene]amino}-1H-1,2,4-triazole-5(4H)-thione

Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 13;69(Pt 5):o718-9. doi: 10.1107/S1600536813009690. Print 2013 May 1.

Authors

B K Sarojini¹, P S Manjula, Gurumurthy Hegde, Dalbir Kour, Vivek K Gupta, Rajni Kant

Affiliation

¹ Department of Chemistry, PA College of Engineering, Nadupadavu 574 153, D.K. Mangalore, India.

Abstract

In the title mol-ecule, C11H12N4S2, the dihedral angle between the triazole and benzene rings is 21.31 (5)°. A weak intra-molecular C-H⋯S hydrogen bond generates an S(6) ring motif. In the crystal, pairs of N-H⋯S hydrogen bonds form inversion dimers. In addition, π-π inter-actions are observed between the benzene rings, with a centroid-centroid separation of 3.7599 (11) Å.