3,4-Di-amino-pyridinium hydrogen malonate

Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 10;69(Pt 5):o670. doi: 10.1107/S1600536813008763. Print 2013 May 1.

Abstract

In the title salt, C5H8N3 (+)·C3H3O4 (-), the 3,4-di-amino-pyridinium cation is almost planar, with an r.m.s. deviation of 0.02 Å. The conformation of the hydrogen malonate anion is stabilized by an intra-molecular O-H⋯O hydrogen bond, which generates an S(6) ring. In the crystal, N-H⋯O hydrogen bonds link cations and anions into layers parallel to the ab plane.