Transport and accumulation of ferrocene tagged poly(vinyl chloride) at the buried interfaces of plasticized membrane electrodes

Manzar Sohail; Roland De Marco; Muhammad Tanzirul Alam; Marcin Pawlak; Eric Bakker

doi:10.1039/c3an00464c

Transport and accumulation of ferrocene tagged poly(vinyl chloride) at the buried interfaces of plasticized membrane electrodes

Analyst. 2013 Aug 7;138(15):4266-9. doi: 10.1039/c3an00464c. Epub 2013 May 29.

Authors

Manzar Sohail¹, Roland De Marco, Muhammad Tanzirul Alam, Marcin Pawlak, Eric Bakker

Affiliation

¹ Faculty of Science, Health, Education and Engineering, University of the Sunshine Coast, 90 Sippy Downs Drive, Sippy Downs, Queensland 4556, Australia.

PMID: 23714844
DOI: 10.1039/c3an00464c

Abstract

Cyclic voltammetry (CV), synchrotron radiation-X-ray photoelectron spectroscopy (SR-XPS) and near edge X-ray absorption fine structure (NEXAFS) show that oxidation of ferrocene tagged PVC induces an accumulation of high molecular weight polymer at the buried interface between the substrate electrode and the plasticized membrane.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Biological Transport / physiology
Electrodes
Ferrous Compounds / analysis
Ferrous Compounds / metabolism*
Metallocenes
Photoelectron Spectroscopy / methods
Plasticizers / chemistry*
Polyvinyl Chloride / analysis
Polyvinyl Chloride / metabolism*

Substances

Ferrous Compounds
Metallocenes
Plasticizers
Polyvinyl Chloride
ferrocene