Pyridine-based dicarbene ligand: synthesis and structure of a bis-2-pyridylidene palladium complex

Chem Commun (Camb). 2013 Jun 25;49(50):5648-50. doi: 10.1039/c3cc42655f. Epub 2013 May 17.

Abstract

We herein report the synthesis of a bis-2-pyridylidene palladium(II) complex as an isoelectronic structure of the well-known 2,2'-bipyridine complexes. One-pot or stepwise C-Cl oxidative addition followed by base-mediated C-H palladation of the chlorobipyridine dication to palladium(0) yielded the bis-2-pyridylidene palladium(II) carbonate smoothly.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Coordination Complexes / chemistry*
  • Ligands
  • Molecular Structure
  • Palladium / chemistry*
  • Pyridines / chemistry*

Substances

  • Coordination Complexes
  • Ligands
  • Pyridines
  • Palladium