Abstract
High yields of epoxides were obtained in the oxidation of a large range of olefins using 1.2-2 equiv. of H2O2 in the presence of iron helmet phthalocyanines. The involvement of high-valent iron oxo species was evidenced using cryospray mass spectrometry.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkenes / chemistry*
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Catalysis
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Epoxy Compounds / chemical synthesis*
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Epoxy Compounds / chemistry
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Ferric Compounds / chemistry*
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Hydrogen Peroxide / chemistry*
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Indoles / chemistry*
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Isoindoles
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Molecular Structure
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Quantum Theory
Substances
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Alkenes
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Epoxy Compounds
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Ferric Compounds
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Indoles
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Isoindoles
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Hydrogen Peroxide
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phthalocyanine