Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex

Chem Commun (Camb). 2013 Jun 14;49(47):5378-80. doi: 10.1039/c3cc00244f.

Abstract

A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The Mn(IV)=O adduct is capable of activating C-H bonds by a H-atom transfer mechanism and is more reactive in this regard than most Mn(IV)=O species.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Coordination Complexes / chemistry*
  • Manganese / chemistry*
  • Oxygen / chemistry*
  • Spectrum Analysis
  • X-Ray Diffraction

Substances

  • Coordination Complexes
  • Manganese
  • Oxygen