4-[5-(4-Fluoro-phen-yl)-1-(4-phenyl-1,3-thia-zol-2-yl)-4,5-dihydro-1H-pyrazol-3-yl]-5-methyl-1-(4-methyl-phenyl)-1H-1,2,3-triazole

Bakr F Abdel-Wahab; Seik Weng Ng; Edward R T Tiekink

doi:10.1107/S1600536813008179

4-[5-(4-Fluoro-phen-yl)-1-(4-phenyl-1,3-thia-zol-2-yl)-4,5-dihydro-1H-pyrazol-3-yl]-5-methyl-1-(4-methyl-phenyl)-1H-1,2,3-triazole

Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 28;69(Pt 4):o618. doi: 10.1107/S1600536813008179. Print 2013 Apr 1.

Authors

Bakr F Abdel-Wahab¹, Seik Weng Ng, Edward R T Tiekink

Affiliation

¹ Applied Organic Chemistry Department, National Research Centre, Dokki, 12622 Giza, Egypt.

Abstract

In the title compound, C28H23FN6S, the pyrazole ring adopts an envelope conformation, with the methine C atom being the flap atom. With respect to this ring, the 2-thienyl, triazole and fluoro-benzene rings are approximately coplanar, coplanar and perpendicular, respectively [dihedral angles = 8.56 (17), 6.03 (19) and 73.1 (2)°, respectively] so that to a first approximation the mol-ecule has a T-shape. In the crystal, mol-ecules are consolidated into a three-dimensional architecture by C-H⋯F (involving a bifurcated F atom), C-H⋯S and C-H⋯π inter-actions.