Nanohinge-induced plasticity of helical carbon nanotubes

Small. 2013 Nov 11;9(21):3561-6. doi: 10.1002/smll.201202830. Epub 2013 Apr 30.

Abstract

Helical carbon nanotubes with intentionally incorporated non-hexagonal defects have unexpectedly high toughness and plasticity, in addition to the well-recognized extreme elasticity. The obtained toughness approaches 5000 J g(-1) with decreasing spring radius. The high toughness originates from the plastic nanohinge formation as a result of distributed partial fractures. A strong spring size effect, contradictory to the continuum solution, is precisely described by an atomistic bond-breaking model.

Keywords: Helical carbon nanotube; gravimetric toughness; partial fracture; plastic nanohinge; plasticity; size effect.