Preparation of aligned Eu(DBM)3phen/PS fibers by electrospinning and their luminescence properties

Hongquan Yu; Tao Li; Baojiu Chen; Yanbo Wu; Yue Li

doi:10.1016/j.jcis.2013.03.017

Preparation of aligned Eu(DBM)3phen/PS fibers by electrospinning and their luminescence properties

J Colloid Interface Sci. 2013 Jun 15:400:175-80. doi: 10.1016/j.jcis.2013.03.017. Epub 2013 Mar 22.

Authors

Hongquan Yu¹, Tao Li, Baojiu Chen, Yanbo Wu, Yue Li

Affiliation

¹ College of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian, Liaoning, PR China. yuhq7808@yahoo.com.cn

PMID: 23578517
DOI: 10.1016/j.jcis.2013.03.017

Abstract

Electrospinning is a technique employed to prepare nanofibers of polymer, ceramics, and composite that are used in the high electrostatic field. Alignment is an important step toward the exploitation and applications of these fibers. In the present report, super-long aligned luminescent composite Eu(DBM)3phen/PS fibers (DBM=dibenzoylmethane, phen=1,10-phenanthroline, PS=polystyrene) were prepared via an electrospinning method. The key to the success of this method was the usage of high molecular weight PS (Mw=4.4×10(5)) in the electrospinning solution and the low speed (>0.5 m/s) collecting drum. Luminescent properties of the composite fibers were systemically studied in comparison with that of the corresponding pure europium complex Eu(DBM)3phen. The results showed that the fluorescence lifetime of (5)D0 state and the luminescent intensity of Eu(3+) in Eu(DBM)3phen/PS composite fibers increased gradually with the fiber diameter. The composite fibers with smaller diameter exhibited better photoluminescence stability than that of the pure complex Eu(DBM)3phen.