Abstract
The Ru(II)-H and water promoted asymmetric cleavage of 2,2'-pyridil to pyridine-2-carbaldehyde and unprecedented picolinic acid anion radical (PyCOOH(-)˙) complexes, which in solution produce H2 gas and diamagnetic picolinate complexes of ruthenium(II) in moderate yields, is reported.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Anions / chemical synthesis
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Anions / chemistry
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Free Radicals / chemical synthesis
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Free Radicals / chemistry
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Hydrogen / chemistry*
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Models, Molecular
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Molecular Structure
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Picolinic Acids / chemical synthesis*
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Picolinic Acids / chemistry
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Pyridines / chemical synthesis
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Pyridines / chemistry*
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Ruthenium / chemistry*
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Water / chemistry*
Substances
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Anions
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Free Radicals
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Picolinic Acids
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Pyridines
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pyridine-2-carbaldehyde
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Water
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Ruthenium
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Hydrogen
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pyridine
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picolinic acid