Abstract
The synthesis and structural characterisation of the uranium(IV) amido-borohydrides (N'')2U{κ(2)-N(SiMe3)SiMe2CH2BBN-H} and U{κ(2)-N(SiMe3)SiMe2CH2BBN-H}2, and their activity as pre-catalysts for the polymerisation of isoprene are described.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Amides / chemistry*
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Borohydrides / chemistry*
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Butadienes / chemistry*
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Catalysis
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Hemiterpenes / chemical synthesis*
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Hemiterpenes / chemistry*
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Latex / chemical synthesis*
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Latex / chemistry
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
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Pentanes / chemistry*
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Polymerization
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Uranium / chemistry*
Substances
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Amides
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Borohydrides
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Butadienes
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Hemiterpenes
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Latex
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Organometallic Compounds
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Pentanes
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isoprene
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Uranium
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1,4-polyisoprene