Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals

Kyung Hwan Park; Tae Hwan Noh; Yoon-Bo Shim; Ok-Sang Jung

doi:10.1039/c3cc00005b

Construction of right-handed-, left-handed-, and racemic helical coordination polymers. Enantioselective recognition using chiral helical crystals

Chem Commun (Camb). 2013 May 11;49(38):4000-2. doi: 10.1039/c3cc00005b. Epub 2013 Apr 5.

Authors

Kyung Hwan Park¹, Tae Hwan Noh, Yoon-Bo Shim, Ok-Sang Jung

Affiliation

¹ Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University, Pusan 609-735, Korea.

PMID: 23560276
DOI: 10.1039/c3cc00005b

Abstract

Infinite square-tubular helices, [CuCl2(L)(S)] (L = bis(4-pyridyl)methylvinylsilane; S = Me2SO, HCONMe2), were constructed. This helical system affords three kinds of P, M crystals in Me2SO, and racemic crystals in HCONMe2. The cyclic voltammogram (CV) technique using the M-crystals is an effective tool for discerning the chirality of proline.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Copper / chemistry*
Crystallization
Crystallography, X-Ray
Dimethyl Sulfoxide / chemistry
Dimethylformamide / chemistry
Models, Molecular
Polymers / chemistry*
Proline / chemistry*
Silanes / chemistry*
Stereoisomerism

Substances

Polymers
Silanes
Copper
Dimethylformamide
Proline
cupric chloride
Dimethyl Sulfoxide